Many nutrients required by plants exist in soil as basic cations:
A soil's cation-exchange capacity is a measure of its ability to adsorb these basic cations as well as exchangeable hydrogen and aluminum ions. The cation-exchange capacity of soil is derived from two sources: small clay particles called micelles consisting of alternating layers of alumina and silica crystals, and organic colloids.
Replacement of + and + by other cations of lower valence creates a net negative charge within the inner layers of the micelles. This is called the soil's permanent charge. For example, replacement of an atom of aluminum by calcium within a section where the net charge was previously zero, as shown below, produces a net charge of ?, to which other cations can become adsorbed.
Figure 1
A pH-dependent charge develops when hydrogen dissociates from hydroxyl moieties on the outer surfaces of the clay micelles. This leaves negatively-charged oxygen atoms to which basic cations may adsorb. Likewise, a large pH-
dependent charge develops when hydrogen dissociates from carboxylic acids and phenols in organic matter.
In most clays, permanent charges brought about by substitution account for anywhere from half to nearly all of the total cation-exchange capacity. Soils very high in organic matter contain primarily pH-dependent charges. In a research study,
three samples of soil were leached with a 1 N solution of neutral KCl, and the displaced A13+ and basic cations measured. The sample was then leached again with a buffered solution of BaCl2 and triethanolamine at pH 8.2, and the
displaced H+ measured. Table 1 gives results for three soils tested by this method.
Table 1
Due to the buffering effect of the soil's cation exchange capacity, just measuring the soil solution's pH will not indicate how much base is needed to change the soil pH. In another experiment, measured amounts of acid and base were added to 10-gram samples of well-mixed soil that had been collected from various locations in a field. The volumes of the samples were equalized by adding water. The results were recorded in Figure 2.
Figure 2.
Solution X boils at 100.26°C and solution Y boils at 101.04°C. Both solutions are at atmospheric pressure and contain the same solute concentration. Which of the following conclusions can be drawn?
A. The freezing point of solution X is lower than that of solution Y.
B. The vapor pressure of solution X is higher than that of solution Y at 100.26°C.
C. C. Solution X and solution Y are immiscible.
D. The vapor pressure of solution X is lower than that of solution Y at 100.26°C.
Many nutrients required by plants exist in soil as basic cations:
A soil's cation-exchange capacity is a measure of its ability to adsorb these basic cations as well as exchangeable hydrogen and aluminum ions. The cation-exchange capacity of soil is derived from two sources: small clay particles called micelles consisting of alternating layers of alumina and silica crystals, and organic colloids.
Replacement of + and + by other cations of lower valence creates a net negative charge within the inner layers of the micelles. This is called the soil's permanent charge. For example, replacement of an atom of aluminum by calcium within a section where the net charge was previously zero, as shown below, produces a net charge of ?, to which other cations can become adsorbed.
Figure 1
A pH-dependent charge develops when hydrogen dissociates from hydroxyl moieties on the outer surfaces of the clay micelles. This leaves negatively-charged oxygen atoms to which basic cations may adsorb. Likewise, a large pH-
dependent charge develops when hydrogen dissociates from carboxylic acids and phenols in organic matter.
In most clays, permanent charges brought about by substitution account for anywhere from half to nearly all of the total cation-exchange capacity. Soils very high in organic matter contain primarily pH-dependent charges. In a research study,
three samples of soil were leached with a 1 N solution of neutral KCl, and the displaced A13+ and basic cations measured. The sample was then leached again with a buffered solution of BaCl2 and triethanolamine at pH 8.2, and the
displaced H+ measured. Table 1 gives results for three soils tested by this method.
Table 1
Due to the buffering effect of the soil's cationexchange capacity, just measuring the soil solution's pH will not indicate how much base is needed to change the soil pH. In another experiment, measured amounts of acid and base were added to 10-gram samples of well-mixed soil that had been collected from various locations in a field. The volumes of the samples were equalized by adding water. The results were recorded in Figure 2.
Figure 2.
Which of the following would probably NOT displace + in soil micelles?
A. Option A
B. Option B
C. Option C
D. Option D
Many nutrients required by plants exist in soil as basic cations:
A soil's cation-exchange capacity is a measure of its ability to adsorb these basic cations as well as exchangeable hydrogen and aluminum ions. The cation-exchange capacity of soil is derived from two sources: small clay particles called micelles consisting of alternating layers of alumina and silica crystals, and organic colloids.
Replacement of + and + by other cations of lower valence creates a net negative charge within the inner layers of the micelles. This is called the soil's permanent charge. For example, replacement of an atom of aluminum by calcium within a section where the net charge was previously zero, as shown below, produces a net charge of ?, to which other cations can become adsorbed.
Figure 1
A pH-dependent charge develops when hydrogen dissociates from hydroxyl moieties on the outer surfaces of the clay micelles. This leaves negatively-charged oxygen atoms to which basic cations may adsorb. Likewise, a large pH-
dependent charge develops when hydrogen dissociates from carboxylic acids and phenols in organic matter.
In most clays, permanent charges brought about by substitution account for anywhere from half to nearly all of the total cation-exchange capacity. Soils very high in organic matter contain primarily pH-dependent charges. In a research study,
three samples of soil were leached with a 1 N solution of neutral KCl, and the displaced A13+ and basic cations measured. The sample was then leached again with a buffered solution of BaCl2 and triethanolamine at pH 8.2, and the
displaced H+ measured. Table 1 gives results for three soils tested by this method.
Table 1
Due to the buffering effect of the soil's cationexchange capacity, just measuring the soil solution's pH will not indicate how much base is needed to change the soil pH. In another experiment, measured amounts of acid and base were added to 10-gram samples of well-mixed soil that had been collected from various locations in a field. The volumes of the samples were equalized by adding water. The results were recorded in Figure 2.
Figure 2.
Anaerobic organisms are able to denitrify wet soils by the following metabolic pathway.
If all the oxygen in the nitric acid is converted to water, how many additional equivalents of acid will be consumed during the production of 5 M of nitrogen?
A. 20
B. 30
C. 40
D. 50
Many nutrients required by plants exist in soil as basic cations:
A soil's cation-exchange capacity is a measure of its ability to adsorb these basic cations as well as exchangeable hydrogen and aluminum ions. The cation-exchange capacity of soil is derived from two sources: small clay particles called micelles consisting of alternating layers of alumina and silica crystals, and organic colloids.
Replacement of + and + by other cations of lower valence creates a net negative charge within the inner layers of the micelles. This is called the soil's permanent charge. For example, replacement of an atom of aluminum by calcium within a section where the net charge was previously zero, as shown below, produces a net charge of ?, to which other cations can become adsorbed.
Figure 1
A pH-dependent charge develops when hydrogen dissociates from hydroxyl moieties on the outer surfaces of the clay micelles. This leaves negatively-charged oxygen atoms to which basic cations may adsorb. Likewise, a large pH-
dependent charge develops when hydrogen dissociates from carboxylic acids and phenols in organic matter.
In most clays, permanent charges brought about by substitution account for anywhere from half to nearly all of the total cation-exchange capacity. Soils very high in organic matter contain primarily pH-dependent charges. In a research study,
three samples of soil were leached with a 1 N solution of neutral KCl, and the displaced A13+ and basic cations measured. The sample was then leached again with a buffered solution of BaCl2 and triethanolamine at pH 8.2, and the
displaced H+ measured. Table 1 gives results for three soils tested by this method.
Table 1
Due to the buffering effect of the soil's cation exchange capacity, just measuring the soil solution's pH will not indicate how much base is needed to change the soil pH. In another experiment, measured amounts of acid and base were added to 10-gram samples of well-mixed soil that had been collected from various locations in a field. The volumes of the samples were equalized by adding water. The results were recorded in Figure 2.
Figure 2.
The amount of soil on a particular one-acre field down to a depth of one furrow slice weighs 9 ?105 kilograms. Based on Figure 2, how many kilograms of CaCO3 would have to be added to this field to raise the pH from 5 to 6?
A. Option A
B. Option B
C. Option C
D. Option D
Many nutrients required by plants exist in soil as basic cations:
A soil's cation-exchange capacity is a measure of its ability to adsorb these basic cations as well as exchangeable hydrogen and aluminum ions. The cation-exchange capacity of soil is derived from two sources: small clay particles called micelles consisting of alternating layers of alumina and silica crystals, and organic colloids.
Replacement of + and + by other cations of lower valence creates a net negative charge within the inner layers of the micelles. This is called the soil's permanent charge. For example, replacement of an atom of aluminum by calcium within a section where the net charge was previously zero, as shown below, produces a net charge of ?, to which other cations can become adsorbed.
Figure 1
A pH-dependent charge develops when hydrogen dissociates from hydroxyl moieties on the outer surfaces of the clay micelles. This leaves negatively-charged oxygen atoms to which basic cations may adsorb. Likewise, a large pH-
dependent charge develops when hydrogen dissociates from carboxylic acids and phenols in organic matter.
In most clays, permanent charges brought about by substitution account for anywhere from half to nearly all of the total cation-exchange capacity. Soils very high in organic matter contain primarily pH-dependent charges. In a research study,
three samples of soil were leached with a 1 N solution of neutral KCl, and the displaced A13+ and basic cations measured. The sample was then leached again with a buffered solution of BaCl2 and triethanolamine at pH 8.2, and the
displaced H+ measured. Table 1 gives results for three soils tested by this method.
Table 1
Due to the buffering effect of the soil's cationexchange capacity, just measuring the soil solution's pH will not indicate how much base is needed to change the soil pH. In another experiment, measured amounts of acid and base were added to 10-gram samples of well-mixed soil that had been collected from various locations in a field. The volumes of the samples were equalized by adding water. The results were recorded in Figure 2.
Figure 2.
What would be the effect of leaching the three soil samples in Table 1 with a buffered BaCl2 solution at pH 9.5 instead of 8.3?
A. The measured permanent charge would be greater.
B. The measured pH-dependent charge would be greater.
C. The measured permanent charge would be smaller.
D. The measured pH-dependent charge would be smaller.
Many nutrients required by plants exist in soil as basic cations:
A soil's cation-exchange capacity is a measure of its ability to adsorb these basic cations as well as exchangeable hydrogen and aluminum ions. The cation-exchange capacity of soil is derived from two sources: small clay particles called micelles consisting of alternating layers of alumina and silica crystals, and organic colloids.
Replacement of + and + by other cations of lower valence creates a net negative charge within the inner layers of the micelles. This is called the soil's permanent charge. For example, replacement of an atom of aluminum by calcium within a section where the net charge was previously zero, as shown below, produces a net charge of ?, to which other cations can become adsorbed.
Figure 1
A pH-dependent charge develops when hydrogen dissociates from hydroxyl moieties on the outer surfaces of the clay micelles. This leaves negatively-charged oxygen atoms to which basic cations may adsorb. Likewise, a large pH-
dependent charge develops when hydrogen dissociates from carboxylic acids and phenols in organic matter.
In most clays, permanent charges brought about by substitution account for anywhere from half to nearly all of the total cation-exchange capacity. Soils very high in organic matter contain primarily pH-dependent charges. In a research study,
three samples of soil were leached with a 1 N solution of neutral KCl, and the displaced A13+ and basic cations measured. The sample was then leached again with a buffered solution of BaCl2 and triethanolamine at pH 8.2, and the
displaced H+ measured. Table 1 gives results for three soils tested by this method.
Table 1
Due to the buffering effect of the soil's cation exchange capacity, just measuring the soil solution's pH will not indicate how much base is needed to change the soil pH. In another experiment, measured amounts of acid and base were added to 10-gram samples of well-mixed soil that had been collected from various locations in a field. The volumes of the samples were equalized by adding water. The results were recorded in Figure 2.
Figure 2.
Which soil from Table 1 most likely has the highest percentage of organic matter?
A. Sample I
B. Sample II
C. Sample III
D. Cannot be determined
Many nutrients required by plants exist in soil as basic cations:
A soil's cation-exchange capacity is a measure of its ability to adsorb these basic cations as well as exchangeable hydrogen and aluminum ions. The cation-exchange capacity of soil is derived from two sources: small clay particles called micelles consisting of alternating layers of alumina and silica crystals, and organic colloids.
Replacement of + and + by other cations of lower valence creates a net negative charge within the inner layers of the micelles. This is called the soil's permanent charge. For example, replacement of an atom of aluminum by calcium within a section where the net charge was previously zero, as shown below, produces a net charge of ?, to which other cations can become adsorbed.
Figure 1
A pH-dependent charge develops when hydrogen dissociates from hydroxyl moieties on the outer surfaces of the clay micelles. This leaves negatively-charged oxygen atoms to which basic cations may adsorb. Likewise, a large pH-
dependent charge develops when hydrogen dissociates from carboxylic acids and phenols in organic matter.
In most clays, permanent charges brought about by substitution account for anywhere from half to nearly all of the total cation-exchange capacity. Soils very high in organic matter contain primarily pH-dependent charges. In a research study,
three samples of soil were leached with a 1 N solution of neutral KCl, and the displaced A13+ and basic cations measured. The sample was then leached again with a buffered solution of BaCl2 and triethanolamine at pH 8.2, and the
displaced H+ measured. Table 1 gives results for three soils tested by this method.
Table 1
Due to the buffering effect of the soil's cationexchange capacity, just measuring the soil solution's pH will not indicate how much base is needed to change the soil pH. In another experiment, measured amounts of acid and base were added to 10-gram samples of well-mixed soil that had been collected from various locations in a field. The volumes of the samples were equalized by adding water. The results were recorded in Figure 2.
Figure 2.
What percentage of the cation exchange capacity of Sample I is base-saturated?
A. 4%
B. 6%
C. 29%
D. 40%
The periodic beating of the heart is controlled by electrical impulses that originate within the cardiac muscle itself. These pulses travel to the sinoatrial node and from there to the atria and the ventricles, causing the cardiac muscles to contract. If a current of a few hundred milliamperes passes through the heart, it will interfere with this natural system, and may cause the heart to beat erratically. This condition is known as ventricular fibrillation, and is life-threatening. If, however, a larger current of about 5 to 6 amps is passed through the heart, a sustained ventricular contraction will occur. The cardiac muscle cannot relax, and the heart stops beating. If at this point the muscle is allowed to relax, a regular heartbeat will
usually resume.
The large current required to stop the heart is supplied by a device known as a defibrillator. A schematic diagram of a defibrillator is shown below. This device is essentially a "heavy-duty" capacitor capable of storing large amounts of energy. To charge the capacitor quickly (in 1 to 3 seconds), a large DC voltage must be applied to the plates of the capacitor. This is achieved using a step-up transformer, which creates an output voltage that is much larger than the input voltage. The transformer used in this defibrillator has a step-up ratio of 1:50.
The AC voltage that is obtained from the transformer must then be converted to DC voltage in order to charge the capacitor. This is accomplished using a diode, which allows current flow in one direction only. Once the capacitor is fully charged, the charge remains stored until the switch is moved to position B and the plates are placed on the patient's chest. To cut down the resistance between the patient's body and the defibrillator, the electrodes are covered with a wetting gel before use. Care must be taken to insure that the patient is not in electrical contact with the ground while the defibrillator is in use.
If a dielectric was inserted between the plates of the capacitor in the defibrillator when the switch is in position A:
A. the energy stored in the capacitor would increase.
B. the energy stored in the capacitor would decrease.
C. the electric field between the plates would increase.
D. the electric field between the plates would decrease.
Many nutrients required by plants exist in soil as basic cations:
A soil's cation-exchange capacity is a measure of its ability to adsorb these basic cations as well as exchangeable hydrogen and aluminum ions. The cation-exchange capacity of soil is derived from two sources: small clay particles called micelles consisting of alternating layers of alumina and silica crystals, and organic colloids.
Replacement of + and + by other cations of lower valence creates a net negative charge within the inner layers of the micelles. This is called the soil's permanent charge. For example, replacement of an atom of aluminum by calcium within a section where the net charge was previously zero, as shown below, produces a net charge of ?, to which other cations can become adsorbed.
Figure 1
A pH-dependent charge develops when hydrogen dissociates from hydroxyl moieties on the outer surfaces of the clay micelles. This leaves negatively-charged oxygen atoms to which basic cations may adsorb. Likewise, a large pH-
dependent charge develops when hydrogen dissociates from carboxylic acids and phenols in organic matter.
In most clays, permanent charges brought about by substitution account for anywhere from half to nearly all of the total cation-exchange capacity. Soils very high in organic matter contain primarily pH-dependent charges. In a research study,
three samples of soil were leached with a 1 N solution of neutral KCl, and the displaced A13+ and basic cations measured. The sample was then leached again with a buffered solution of BaCl2 and triethanolamine at pH 8.2, and the
displaced H+ measured. Table 1 gives results for three soils tested by this method.
Table 1
Due to the buffering effect of the soil's cation exchange capacity, just measuring the soil solution's pH will not indicate how much base is needed to change the soil pH. In another experiment, measured amounts of acid and base were added to 10-gram samples of well-mixed soil that had been collected from various locations in a field. The volumes of the samples were equalized by adding water. The results were recorded in Figure 2.
Figure 2.
Which column(s) in Table 1 represent(s) the permanent charge of the soil micelles?
A. Option A
B. Option B
C. Option C
D. Option D
The periodic beating of the heart is controlled by electrical impulses that originate within the cardiac muscle itself. These pulses travel to the sinoatrial node and from there to the atria and the ventricles, causing the cardiac muscles to contract. If a current of a few hundred milliamperes passes through the heart, it will interfere with this natural system, and may cause the heart to beat erratically. This condition is known as ventricular fibrillation, and is life-threatening. If, however, a larger current of about 5 to 6 amps is passed through the heart, a sustained ventricular contraction will occur. The cardiac muscle cannot relax, and the heart stops beating. If at this point the muscle is allowed to relax, a regular heartbeat will usually resume.
The large current required to stop the heart is supplied by a device known as a defibrillator. A schematic diagram of a defibrillator is shown below. This device is essentially a "heavy-duty" capacitor capable of storing large amounts of energy. To charge the capacitor quickly (in 1 to 3 seconds), a large DC voltage must be applied to the plates of the capacitor. This is achieved using a step-up transformer, which creates an output voltage that is much larger than the input voltage. The transformer used in this defibrillator has a step-up ratio of 1:50.
The AC voltage that is obtained from the transformer must then be converted to DC voltage in order to charge the capacitor. This is accomplished using a diode, which allows current flow in one direction only. Once the capacitor is fully
charged, the charge remains stored until the switch is moved to position B and the plates are placed on the patient's chest. To cut down the resistance between the patient's body and the defibrillator, the electrodes are covered with a wetting
gel before use. Care must be taken to insure that the patient is not in electrical contact with the ground while the defibrillator is in use.
The plates of the capacitor are originally separated by a vacuum. If a dielectric K>1 is introduced between the plates of the capacitor, and the capacitor is allowed to charge up, which of the following statements is/are true?
I) The capacitance of the capacitor will increase.
II) The voltage across the capacitor plates will increase.
III) The charge stored on the capacitor will increase.
A. I only
B. I and II only
C. II and III only
D. I and III only
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